Molybdenum Sheets, Plates

Molybdenum Sheets, Plates

01
Description
JSC POLEMA produces sintered and deformed semi-finished products (sheets, rods), plates, electrodes for melting glass, sputtering targets, trays and other parts, using oxide-reduced molybdenum powder with purity of 99.95-99.97% as the raw material.

Thanks to the low content of interstitial impurities and metallic impurities and the small-grain texture of the material, the finished products boast outstanding plastic properties.

Some of molybdenum's important features in terms of its industrial application include its high heat resistance, electric conductivity and heat conductivity, its relatively low thermal neutron capture cross-section with a volume weight almost twice lower than that of tungsten, etc. Molybdenum's resistance to creep and stress-rupture at high temperatures in a vacuum and in protective atmosphere (argon, hydrogen) is noticeably higher than the same properties of many metals used as the base for heat-resistant materials.

As a result of molybdenum's low temperature coefficient of linear expansion and its high melting point, it ensures the dependable functionality of structures made from molybdenum that operate at high temperatures.

Molybdenum's high thermal conductivity is several times greater than that of ordinarily used heat-resistant alloys, which prevents thermal stresses during rapid heating and cooling.

Molybdenum is resistant to the effects of acids, alkalis and resistive in many molten metals and liquid glasses.
02
specifications

1. Mo-PM alloy sheets


Dimensions, mechanical and structural characteristics, surface quality


Mo-PM rolled products are made:


  • - with finishing by pressure shaping: hot-rolled (HR) with a thickness of 1-45 mm and cold-rolled (CR) with a thickness of 0.3 (0.2)-0.9 mm;

  • - based on the degree of rolling accuracy: products of normal and enhanced accuracy;

  • - based on materials used, hot-rolled sheets – annealed or without annealing with a surface cleansed of oxides, based on the client's order;

  • - in moderate dimensions with scissor-trimmed edges, or a plate with a mechanically milled or grinded surface with a thickness of more than 5 mm;

  • - with monitoring of the surface condition, mechanical properties and microstructure.

Dimensions and mechanical properties of Mo-PM grade sheets and plates


Thickness s,
mm
Tolerances s,
mm
Width,
mm
Length, 
mm
σв, Н/ mm 2 (kgf/ mm 2 ),
min
δ, %,
min
0,2-0,4 ± 0,05 (0,03) 50-300 150-1000 * *
0,5-0,7 ± 0,05 50-500 150-1350 * *
0,8-0,9 ± 0,08 50-500 150-1350 690 (70) 8
1,0-2,0 +0,20-0,15 50-600 150-1600 690(70) 8
2,2-4,0 +0,25-0,15 50-600 150-1250 690(70) 10
4,5-6,0 +0,30-0,20 50-600 150-1000 640 (65) 8
6,5-10,0 ± 0,40 100-600 >150 ** **
10,5-20,0 ± 1,0 100-400 >150 ** **
20,5-30,0 ± 1,5 100-400 >150 ** **
30-45
According to the drawings agreed with the customer

Upon agreement with the client, sheets are delivered without determining their mechanical properties. In this case, the manufacturer guarantees mechanical properties in keeping with the standard.

* Sheets with a thickness of 0.7 and more are tangent bending-tested for parallelness with the following thicknesses in mm:

- 5 – for sheets with a thickness of > 0.2 to 0.5 mm;

- 8 – for sheets with a thickness of > 0.5 to 0.7 mm, inclusive.


** Mechanical properties of sheets (plates) with a thickness of more than 6 mm are determined at the client's request.


Norms are set based on agreement with the client.


Non-flatness:


  • - of sheets with a thickness of 1-3 mm does not exceed 2 mm per 100 mm of length;
  • - of sheets with a thickness of over 3 mm does not exceed 1 mm per 100 mm of length.

Surface condition:


rolled stock is delivered without cracks, slivers, backfins, rolled-in foreign particles, blemishes, or edge lamination.


Annealing to remove internal stress:


hot-rolled sheets are manufactured with annealing to remove internal stress, or without annealing (based on the client's order) with a surface cleansed of oxides.


Microstructure:

in sheets (with a thickness of 1-6 mm), a full recrystalliation structure, lamination and foreign particles, tested for using supersonic defectoscopy, are not allowed.


2. Mo99,95-PM rolled stock

Dimensions, mechanical and structural properties, and surface quality

Mo99,95-PM rolled stock is produced:


  • - based on finishing by pressure treatment – hot-rolled and cold-rolled;

  • - based on the condition of the material – thermally treated, with annealment to remove internal stress, unless the client makes other requests;

  • - based on the client's request – with an untreated surface following rolling, or with a mechanically or chemically cleansed surface, or with a surface treated mechanically with milling or grinding;

  • - based on the condition of the edges – with trimmed edges and ends or, at the client's request, with mechanically treated edges and ends.

Rolled stock dimensions and norms for maximum dimension deviations meet ASTM B 386 standards.

Maximum deviations for thickness of Мo99.95-PM rolled stock

Width, mm Thickness, mm Maximum thickness deviation
305 or less 0,3 - 0,51 ± 0,05 mm
> 0,51 ± 10 %
305 - 610 > 0,64 ± 10 %

  The thickness of rolled stock ranges from 0.3 (0.2) to 45 mm. Maximum width deviations are set based on agreement with the consumer, but do not exceed ±1.6 mm for trimmed sheets and ±0.8 mm for sheets with milled edges.

Maximum widths and lengths of thick sheets and mechanically treated plates prepared from them with a thickness of between 6 and 45 mm are set based on an agreement with the client, depending on his requests (drawings).

Sample dimensions for Mo99.95-PM large-size plates and sheets:

8х127х1575 mm; 8х400х800 mm; 10х305х1000 mm; 12х609х609 mm; 12х190х1470 mm; 16х610х710 mm; 18х244х1010 mm; 42х83х107 mm; 45х95х110 mm. 

Maximum length and camber deviations do not exceed ±1.6 mm for a length of 304.8 mm, unless otherwise requested.

Maximum flatness (waviness) deviations for Mo99.95-PM rolled stock:

  • - < 4% for thicknesses from 0.3 to 4.75 mm;
  • - < 5% for thicknesses from 4.75 to 12.7 mm;
  • - < 8%  for thicknesses from 12,7 mm non machining plates.

Surface condition: rolled stock is delivered without cracks, slivers, backfins, rolled-in foreign particles, or blemishes.

Guaranteed mechanical properties of Мo99.95-PM rolled stock*

Thickness, mm Durability σв, Н/mm(kgf/mm2) Relative elongation δ, %
min
0,33 - 0,5 760 (77) 6
0,5 - 1,5 725 (74) 10
1,5 - 2,5 690 (70) 14
2,5 - 4,75 690 (70) 18
4,75 - 12,7 690 (70) 10
12,7 - 25,4 655 (67) 2**
25,4 - 38 655 (67) 1**

*property norms are established for materials after annealment in a protective atmosphere at a temperature of 900 оС during a 30 minute period


**parameters are determined using samples transverse to the direction of the rolling


Thin sheets with a thickness of less than 1 mm should withstand a bending test to an ordered angle of at least 90о.


Sample values for mechanical properties of molybdenum rolling stock


Thickness, mmDurability σв, kgf/mm2Relative elongation δ, %Hardness НВ
1,0-1,378-85

13-16

217-240
1,9-2,579-8818-21229-240
3,0-5,475-8218-25210-229


Microstructure


The manufacturer monitors the microstructure of rolled sheets. In thin sheets (less than 4.75 mm), no full recrystallization structure is permitted, unless otherwise requested by the client.

03
advantages
Significant production experience
Strict quality control of manufactured products
Own R&D laboratory
Flexible discount system
04
Product names
JSC POLEMA produces sheets and plates of the following grades:


1) Mo-PM grade sheets and plates
2) Mo99,95-PM rolled stock

You can get full list of products by contacting our sales managers.: export_polema@metholding.com тел.:+7 4872 25-06-76.
05
chemical composition
Mo-PM alloy sheets:

Since 2002, the company has primarily used Mo powder 99,95 molybdenum powder to produce sheet products.

Grade Min Мо, %* Chemical composition, ppm, max
Fe Al Ni Si Mg Na K Ca W Mn Zn C ∑Ме**
MP-Мо 99,95 100 30 50 50 20 30 80 40 130 10 5 40 500


*The weight percentage of Mo in MP-Мо powder is determined by subtracting the sum of the metallic impurities from 100%, controlled by Inductively Coupled Plasma Mass Spectrometry (ICP-MS).

The gas-forming impurities C, O, N, H, S, F, Cl are not taken into account in the calculations of the proportion of molybdenum.

** Σ Ме – amount of metallic impurities.


Mo99,95-PM rolled stock:

High-quality raw materials – molybdenum powder with a purity of Mo 99.95-99.98% - are used to make the sintered semifinished products from which sheets are produced.



MP-Мо  Мо, %,
min*
impurities, ppm, max
O N C Fe Al Ni Si Mg Ca ΣМе**
Guaranteed composition 99,95 70 50 100 100 50 50 100 30 70 500
Typical values >99,97 40-70 20-30 15-30 37-45 <10 <10 <10 <10 <10 <300

* Content of the base metal, not including gas-forming elements.

** Σ Ме - total metallic impurities.

06
miscellaneous
By agreement of the parties, the products are delivered without determining the mechanical properties. At the same time, the manufacturer guarantees the mechanical properties established by the standard.

The standards are established by agreement with the customer.
07
Application areas